段文增 副教授

电话：18264508180

E-mail：duanwenzeng@lcu.edu.cn

duanwenzeng@163.com

山东省聊城市东昌府区湖南路1号聊城大学东校区化学化工学院6号实验楼6A509

科研方向：有机合成化学；手性荧光探针合成及应用；面手性CPL功能有机材料研究

讲授课程：有机化学，化学前沿，有机专论实验，有机化学实验。

教育经历:

2000.01-2004.06 聊城大学 学士；

2004.09-2007.06 山东大学 硕士；

2009.09-2013.06 山东大学 博士；

2019.09-2020.07 美国弗吉尼亚大学 访问学者。

科研项目

(1) 国家自然科学基金委员会，青年项目，21801108，新型双功能过渡金属配合物的设计、合成及碳氢键官能团化研究，2019/01-2021/12，26万元，在研，参与。

(2) 山东省自然科学基金委员会，面上项目，ZR2022MB145，以对映选择性识别氨基酸为导向的面手性吡喃酮类荧光探针的设计合成及识别机制研究，2023/01-2025/12，10万元，在研，主持。

(3) 山东省自然科学基金委员会，面上项目，ZR2017MB052，基于面手性[2.2]环仿的新型BODIPY类荧光分子的构筑及发光性质的研究，2017/08-2020/06，13万元，已结题，主持。

(4) 山东省自然科学基金委员会，联合专项项目，ZR2012BL08，具有中心手性和面手性的卡宾催化剂的合成及其催化性能的研究，2013/01-2015/12，4万元，已结题，主持。

论著(第一或通讯作者)一览：

         1- Planar chiral AIEgens based on [2.2]paracyclophane as efficient solid-state deep red circularly polarized luminescent emitters.

Honghan Ji, Wenjing Liu, Yanmin Huo*, Miao Han, Qingxia Yao, Shuwen Gong*, Wenzeng Duan*.

Dyes and Pigments, 2023, 209, 110915.

         2- AIE-active aurones for circularly polarized luminescence and trace water detection.

Wenzeng Duan*, Wenjing Liu, Houting Liu, Honghan Ji, Yanmin Huo, Huaiwei Wang, Shuwen Gong*.

Chem. Commun., 2022, 58, 13955-13958.

         3- Highly sensitive fluorescence response of [2.2]paracyclophane modified D−A type chromophores to trace water, pH, acidic gases and formaldehyde.

Honghan Ji, Wenzeng Duan*, Yanmin Huo, Wenjing Liu, Xianqiang Huang, Yanlan Wang, Shuwen Gong.

Dyes and Pigments, 2022, 205, 110491

         4- 3D Boranil Complexes with Aggregation-Amplified Circularly Polarized Luminescence.

Kang Li, Honghan Ji, Zeren Yang, Wenzeng Duan*, Yudao Ma, Houting Liu, Huaiwei Wang, Shuwen Gong*.

J. Org. Chem., 2021, 86, 16707-16715.

         5- Planar chiral [2.2]paracyclophanyl-based boron fluoride complexes: synthesis, crystal structure and photophysical properties.

Wenzeng Duan*, Honghan Ji, Zeren Yang, Qingxia Yao, Yanmin Huo, Xuerui Ren, Jiaojiao Zhao, Shuwen Gong*

Dalton Trans., 2021, 50, 12963-12969.

         6- Axially chiral propeller-shaped spiroborates with aggregation-modulated circularly polarized luminescence.

Wenzeng Duan*, Kang Li, Honghan Ji, Yanmin Huo, Qingxia Yao, Houting Liu, Shuwen Gong.

Dyes and Pigments, 2021, 193, 109538.

         7- An NHC-CuCl functionalized metal–organic framework for catalyzing β-boration of α,β-unsaturated carbonyl compounds.

Qingxia Yao*, Xiufang Liu, Kaili Liu, Chao Ma, Jie Su, Cong Lin, Dacheng Li, Jianmin Dou, Junliang Sun*, Wenzeng Duan*.

Dalton Trans., 2019, 48, 5144-5148.

         8- Axially chiral 1,4-dihydropyridine derivatives: aggregation-induced emission in exciplexes and application as viscosity probes.

Zeren Yang, Yanmin Huo, Yanke Liu, Guifen Du, Wenhao Zhang, Lijie Zhou, Lihui Zhan, Xuerui Ren, Wenzeng Duan,* Shuwen Gong*.

RSC Adv., 2019, 9, 32219-32225.8

         9- Solvatochromism, acidochromism and aggregation-induced emission of propeller-shaped spiroborates

Kang Li, Jichun Cui, Zeren Yang, Yanmin Huo, Wenzeng Duan*, Shuwen Gong*, Zhipeng Liu*.

Dalton Trans., 2018, 47, 15002-15008.

         10- AIE-active boron complexes based on benzothiazole–hydrazone chelates

Wenzeng Duan, Qingsong Liu, Yanmin Huo, Jichun Cui, Shuwen Gong*, Zhipeng Liu*.

Org. Biomol. Chem., 2018, 16, 4977-4987. (Cover paper)

         11- NHC-Pd complex based on 1,3-bis (4-ethoxycarbonylphenyl) imidazolium chloride: synthesis, structure and catalytic activity in the synthesis of axially chiral benzophenone hydrazone

Wenzeng Duan*, Zhaofeng Sun, Yanmin Huo, Yanke Liu, Guangqing Wu, Ruifeng Wang , Shuang  Wu, Qingxia Yao*, Shuwen Gong*.

Appl. Organometal. Chem., 2018, e4444, 1-6.

         12- Design and synthesis of novel rhodamine-based chemodosimeters derived from [2.2]paracyclophane and their application in detection of Hg2+ ion

Wenzeng Duan, Yinfeng Han, Qingsong Liu, Jichun Cui, Shuwen Gong*, Yudao Ma*, Changli Zhang*, Zhaofeng Sun

Tetrahedron Lett., 2017, 58, 271-278.

         13- Crystal structure studies towards the synthesis and applications of N-heterocyclic carbene–metal complexes derived from [2.2]paracyclophane

Wenzeng Duan, Yudao Ma,* Yanmin Huo, Qingxia Yao

Aust. J. Chem., 2015, 68, 1472-1478.

         14- Synthesis of novel planar chiral Ag and Rh N-heterocyclic carbine complexes derived from [2.2]paracyclophane and their application in ultrasound assisted asymmetric arylation of aldehydes.

Wenzeng Duan, Yudao Ma*, Fuyan He, Lei Zhao, Jianqiang Chen, Chun Song*.

Tetrahedron: Asymmetry., 2013, 24, 241-248. (Cited by Synfacts).

         15- Synthesis of new alkoxy/sulfonate-substituted carbene precursors derived from [2.2]paracyclophane and their application in the asymmetric arylation of aldehydes.

Wenzeng Duan, Yudao Ma*, Bo Qu, Lei Zhao, Jianqiang Chen, Chun Song.

Tetrahedron: Asymmetry, 2012, 23, 1369-1375.

         16- Design and synthesis of planar chiral heterocyclic carbene precursors derived from [2.2]paracyclophane

Wenzeng Duan, Yudao Ma*, Houqi Xia, Xueying Liu, Qingshuang Ma, Junshan Sun

J. Org. Chem., 2008, 73(11), 4330-4333.

专利：

(1). 段文增，刘文静，季洪汉，霍艳敏。一种面手性噢哢及其制备方法、应用，申请号：2022113212332，发明专利，2022。

(2). 段文增，李康，龚树文，霍艳敏。面手性环仿BODIPY的制备及固体荧光应用，CN109735131A，发明专利，2019。

   (3) 段文增，孙君善，程远志，周子腾，李震，韩银锋，候现明，马世营。

基于[2.2] 环 仿 类 罗 丹 明 Hg2+ 荧 光 探 针 材 料 及 其 制 备 方 法 ，CN105400506A，发明专利，2016。

教改论文：

(1) 有机化学专论实验教学改革研究与探索，

段文增*, 赵迎旭, 龚树文, 黄现强, 黄万镇, 杨冰川。

Univ. Chem.(大学化学), 2023, 38, 1-5。

(2). 应用电子效应判断有机化学反应主要产物,

段文增*, 龚树文, 姚清侠, 江新亮, 王飞然。

广州化工，2020,48,124-127.

参加会议情况:

         Kang Li, Wenzeng Duan*, et al. The design and synthesis of chiral AIE-active spiroborates

The 1st Symposium on Aggregation-induced Emission (AIE) of Chinese, 26th-29th September, 2018, Xi’an, China.

         Yanmin Huo, Wenzeng Duan*, et al. The synthesis and crystal structure studies of zinc coordination compounds derived from [2.2]paracyclophanyl carboxylic acid.

CCS•The 9th National Organic Chemistry Conference , 28th-31th July, 2015, Changchun, China.

         Wenzeng Duan*, et al. The synthesis of rhodamine-based fluorescent probe derived from [2.2]paracyclophane.

CCS•The 9th National Organic Chemistry Conference , 28th-31th July, 2015, Changchun, China.

所获奖励：

         山东化学化工学会科学技术奖, 三等奖（第一位）2023.01.

         山东省研究生高端化工与功能材料创新实践大赛，一等奖（指导教师） 2023.

         聊城大学科学技术奖，三等奖，（第二位） 2022.10.

         聊城大学第五届青年教师讲课比赛一等奖 2017.12

          聊城大学第四届青年教师讲课比赛三等奖 2017.01.

         泰安市嘉奖, 2012.06.