王燕兰老师简介

 

wangyanlan@lcu.edu.cn

博士/教授

 

TEL/

EMAIL/ wangyanlan@lcu.edu.cn

    出生日期/ 1985.04.19

 

籍贯/山东聊城

科研方向/金属有机化学,氟化学,  大分子材料化学

 
             讲授课程

 

2017-2018学年硕士研究生《化学专业英语》;

2018-2019学年本科生《有机化学》双语教学

教育经历

2003.09-2007.07,聊城⼤学,化学化工学院,本科学位;

2007.09-2010.03,上海交通⼤学,化学化工学院,张万斌教授课题组, 硕⼠学位;

2010.10-2013.12,  法国波尔多⼤学(Bordeaux University), 化学系(Didier Astruc教授课题组), 博⼠学位 ;

2014.02-2015.10, 法国国家科学中⼼-天然化学物质研究所(CNRS-ICSN)所长Max Malacria教授课题组,博⼠后;

2015.11- 2017.08,牛津大学(Oxford University), Véronique Gouverneur 教授课题组,欧盟⾼级玛丽居⾥学者

(Experienced Marie Curie Fellow-ITN) ;

2017.09- 至今    聊城大学, 化学化工学院, “特聘教授”。

科研项目

2014年获得法国国家科学中心博士后研究项目基金,从事新型三角形全金属芳香化合物的合成和催化应用研究。

2015年获得欧盟玛丽居里研究项目(Marie Curie-ITN-RADIOMI)支持,从事新型氟化试剂,含氟药物中间体以及生物大分子的18F-放射性标记及其在PET-CT显像技术中的应用研究。

2017年获聊城大学“特聘教授”科研启动基金(40万)支持, 从事金属有机及有机大分子材料的合成及应用研究。

获奖情况

获得2009年上海交通大学’天瑞仪器’奖学金,2010年全额博士奖学金,2014年法国国家科学中心博士后奖学金,2015年欧盟高级玛丽居里奖学金及欧盟“高级玛丽居里学者”称号等荣誉,2017年被聘为聊城大学“特聘教授”。迄今为止发表SCI论文二十余篇,包括Nat. Commun.; Angew. Chem.; Chem. Sci. ; Chem. Commun.; Chem. Eur. J. ;Macromolecules ; Organometallics.; Inorg. Chem.等。

论著一览

1-All-metal aromatic cationic palladium triangles can mimic aromatic donor ligands with Lewis acidic cations

Yanlan Wang,  Anna Monfredini,  Pierre-Alexandre Deyris,  Florent Blanchard,  Etienne Derat,  Giovanni Maestri  and  Max Malacria

Chem. Sci.20178, 7394-7402

2-A simple synthesis of triangular all-metal aromatics allowing access to isolobal all-metal heteroaromatics

Yanlan Wang, Pierre-Alexandre Deyris, Tatiana Caneque, Florent Blanchard, Yanling Li, Franca Bigi, Raimondo Maggi, Sebastien Blanchard, Giovanni Maestri and Max Malacria

Chem Eur.J, 201521, 12271-12274

3- Metallodendrimers in three oxidation states with electronically interacting metals and stabilization of size-selected gold nanoparticles

Yanlan Wang, Lionel Salmon, Jaime Ruiz, Didier Astruc

Nature Communications 20145, No. 3489; doi: 10.1038/ncomms4489 (2014).

4- Uncatalyzed hydroamination of electrophilic organometallic alkynes: fundamental, theoretical and applied aspects

Yanlan Wang, Camille Latouche, Amalia Rapakousiou, Colin Lopez, Isabelle Ledoux-Rak, Jaime Ruiz, Jean-Yves Saillard, Didier Astruc

Chem. Eur. J. 201420, 8076-8088.

5- ROMP synthesis of cobalticenium-enamine polyelectrolytes

Yanlan Wang, Amalia Rapakousiou, Didier Astruc

Macromolecules 201447, 3767-3774.

6- Metallation of polyamine dendrimers with ethynylcobalticenium for the construction of mono- and heterobimetallic polycationic metallodendrimers

Yanlan Wang, Amalia Rapakousiou, Jaime Ruiz, Didier Astruc

Chem. Eur. J. 201420, 11176-11186.

7- Poly(Biferrocenylethynyl)arene and bis(biferrocenyl)diynyl complexes and their redox chemistry

Yanlan Wang, Amalia Rapakousiou, Guillaume Chastanet, Lionel Salmon, Jaime Ruiz, and Didier Astruc

Organometallics 201332, 6136-6146.

8- Mild uncatalyzed hydroamination of an electrophilic alkyne ethynylcobalticinium

Yanlan Wang, Amalia Rapakousiou, Camille Latouche, Jean-Claude Daran, Anu Singh, Isabelle Ledoux-Rak, Jaime Ruiz, Jean-Yves Saillardb and Didier Astruc

Chem. Commun., 2013, 49, 5862-5864.

9- Visible-light generation of the naked 12-electron fragment C5H5Fe+: alkyne-to-vinylidene isomerization and synthesis of polynuclear iron vinylidene and alkynyl complexes including hexairon stars.

Yanlan Wang, Abdou K. Diallo, Cátia Ornelas, Jaime Ruiz, and Didier Astruc

Inorg. Chem. 2012, 51, 119-127.

10- Asymmetric hydrogenation of simple ketones with planar chiral ruthenocenyl phosphinooxazoline ligands.

Yanlan Wang, Delong Liu, Qinghua Meng and Wanbin Zhang

Tetrahedron: Asymmetry 200920, 2510-2512.

11- Organoiron-mediated synthesis and redox activity of organoiron-containing dendrimers

Didier Astruc, Yanlan Wang, Amalia Rapakousiou, Abdou K. Diallo, Rodrigue Djeda, Jaime Ruiz, Catia Ornelas

Polyhedron 2015 (C. Lapinte issue), 86, 26-30.

12- Synthesis and redox activity of “Clicked” triazolylbiferrocenyl polymers, network encapsulation of gold and silver nanoparticles and anion sensing

Amalia Rapakousiou, Christophe Deraedt, Joseba Irigoyen, Yanlan Wang, Noel Pinaud, Lionel Salmon, Jaime Ruiz, Sergio Moya, Didier Astruc

Inorg. Chem. 201554, 2284-2299, selected by ACS for open access.

13- Pd-catalyzed asymmetric allylic amination using easily accessible metallocenyl P,N ligands

Hongwei Wu, Fang Xie, Yanlan Wang, Xiaohu Zhao, Delong Liu and Wanbin Zhang

Org. Biomol. Chem.201513, 4248-4254.

14- Click metallodendrimers and their functions

Didier Astruc, Roberto Ciganda, Christophe Deraedt, Sylvain Gatard, Liyuan Liang, Li Na, Catia Ornelas, Amalia Rapakousiou, Jaime Ruiz, Dong Wang, Yanlan Wang, Pengxiang Zhao

Synlett. 201526,1437-1439.

15- Catalytic Semireduction of Internal Alkynes with All-Metal Aromatic Complexes

Pierre-Alexandre Deyris, Tatiana Caneque, Yanlan Wang, Pascal Retailleau, Franca Bigi, Raimondo Maggi, Giovanni Maestri, and Max Malacria

ChemCatChem., 20157, 3266-3269.

16-Multi-function redox polymers: electrochrome, polyelectrolyte, sensor, electrode modifier, nanoparticle stabilizer and catalyst template

Christophe Deraedt, Amalia Rapakousiou, Yanlan Wang, Didier Astruc

Angew. Chem., Int. Ed. 201453, 8445-8449.

17- Click chemistry of an ethynylarene iron complex. syntheses, properties and redox chemistry of cationic bimetallic and dendritic iron-sandwich complexes

Amalia Rapakousiou, Yanlan Wang, Roberto Ciganda, Jean-Michel Lasnier, Didier Astruc

Organometallics 201433, 3583-3590.

18- Mixed-valent metallodendrimers: design and functions

Didier Astruc, Amalia Rapakousiou, Yanlan Wang, Rodrig. Djeda, Abdou K. Diallo, Jaime Ruiz, Catia Ornelas

J. Coord. Chem2014, 67, 3809-3821 (Juan Costamagna issue).

19- Rhodicenium salts from basic chemistry to polyelectrolyte and dendritic macromolecules.

Amalia Rapakousiou, Lucia Herrer Jimenez, Yanlan Wang, Claire Mouche, Didier Astruc

Organometallics201433, 1259-1265.

20- ‘‘Click’’ synthesis and redox activity of a water-soluble triazolylcobalticinium polyelectrolyte

Amalia Rapakousiou, Yanlan Wang, Jaime Ruiz, and Didier Astruc

J. Inorg. Organomet. Polym. Mater. 201424. 107-113.

21– ‘Click’ synthesis and redox properties of triazolyl cobalticinium dendrimers.

Amalia Rapakousiou, Yanlan Wang, Colette Belin, Noel Pinaud, Jaime Ruiz, and Didier Astruc

Inorg. Chem. 2013, 52, 6685-6693.

22– Ferrocenyl dendrimers with ionic tethers and dendrons

Amalia Rapakousiou, Yanlan Wang, Frida Nzulu, Rodrigue Djeda, Noel Pinaud, Jaime Ruiz, and Didier Astruc

Organometallics 201332, 6079-6090.

相关成果

王燕兰教授的研究方向包括有机化学和材料化学,  具有有机合成和金属有机合成,氟化学,不对称催化和功能性大分子材料的合成与应用经验。 研究内容为 : 1)  探索不同功能的树枝状大分子和聚合物对于所稳定的金纳米粒子的尺寸及其催化活性的决定性作用; 2)设计和合成新型三角形全金属芳香化合物M3Ar3+阳离子 , 借助理论计算化学验证该新型金属有机络合物的芳香性,并将其拓展到三角形全金属杂环芳香化合物的合成和应用中;  3) 利用经典有机化学反应,将三氟甲基化试剂进行18F放射性标记,并将其应用到氨基酸,多肽和蛋白质的放射性标记中,以实现其在PET-CT显像技术当中的应用。